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Phosphorescent ligand-to-metal charge-transfer excited states in the group IVB metallocene triad

✍ Scribed by G.V. Loukova; V.A. Smirnov


Book ID
108312054
Publisher
Elsevier Science
Year
2000
Tongue
English
Weight
157 KB
Volume
329
Category
Article
ISSN
0009-2614

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Metal-to-ligand charge-transfer (MLCT) excitation of organometallic and coordination complexes has diverse chemical and physical consequences, depending on the molecular structure and the medium. It can promptly start an ultrafast ligand dissociation, populate a long-lived, charge-separated, 3MLCT s