Mechanistic roles of metal-to-ligand cha
Mechanistic roles of metal-to-ligand charge-transfer excited states in organometallic photochemistry
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AntonΔ±Μn VlΔek Jr.
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Article
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1998
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Elsevier Science
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English
β 314 KB
Metal-to-ligand charge-transfer (MLCT) excitation of organometallic and coordination complexes has diverse chemical and physical consequences, depending on the molecular structure and the medium. It can promptly start an ultrafast ligand dissociation, populate a long-lived, charge-separated, 3MLCT s