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Influence of variations in the chromophoric ligand on the properties of metal-to-ligand charge-transfer excited states

✍ Scribed by Johnson, Susan R.; Westmoreland, T. David; Caspar, Jonathan V.; Barqawi, Khaled R.; Meyer, Thomas J.


Book ID
126431028
Publisher
American Chemical Society
Year
1988
Tongue
English
Weight
766 KB
Volume
27
Category
Article
ISSN
0020-1669

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Metal-to-ligand charge-transfer (MLCT) excitation of organometallic and coordination complexes has diverse chemical and physical consequences, depending on the molecular structure and the medium. It can promptly start an ultrafast ligand dissociation, populate a long-lived, charge-separated, 3MLCT s