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Rigid Medium Stabilization of Metal-to-Ligand Charge Transfer Excited States †

✍ Scribed by Thompson, David W.; Fleming, Cavan N.; Myron, Brent D.; Meyer, Thomas J.


Book ID
120476634
Publisher
American Chemical Society
Year
2007
Tongue
English
Weight
209 KB
Volume
111
Category
Article
ISSN
0022-3654

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Metal-to-ligand charge-transfer (MLCT) excitation of organometallic and coordination complexes has diverse chemical and physical consequences, depending on the molecular structure and the medium. It can promptly start an ultrafast ligand dissociation, populate a long-lived, charge-separated, 3MLCT s