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Phosphorane Iminato Complexes of Manganese and Cobalt with Heterocubane Structure

✍ Scribed by Dipl.-Chem. Hans-Joachim Mai; Dipl.-Chem. Rolf Meyer zu Köcker; Sigrid Wocadlo; Prof. Dr. Werner Massa; Prof. Dr. Kurt Dehnicke

Book ID
101555129
Publisher
John Wiley and Sons
Year
1995
Tongue
English
Weight
252 KB
Volume
34
Category
Article
ISSN
0044-8249

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✦ Synopsis

The phosphorane iminato ligand [NPRJ-, which is

📜 SIMILAR VOLUMES

Phosphoraneiminato Complexes of Manganes
Phosphoraneiminato Complexes of Manganese and Cobalt with Heterocubane Structure
✍ Ulrike Riese; Naim Faza; Werner Massa; Klaus Harms; Thees Breyhan; Paul Knochel; 📂 Article 📅 1999 🏛 John Wiley and Sons 🌐 German ⚖ 135 KB

The phosphoraneiminato complexes [MnBr(NPEt 3 )] 4 (1) and [M 4 Br 5 {NP(NMe 2 ) 3 } 3 ] with M = Mn (2) and M = Co (3) are prepared by melting reactions from the anhydrous metal dibromides with the silylated phosphaneimines Me 3 SiNPR 3 (R = Et, NMe 2 ) in the presence of potassium fluoride. All co