Electronic structure and spectra of nitrosyl complexes with cobalt and manganese porphyrins
β Scribed by Maria Jaworska, Piotr Lodowski
- Book ID
- 120779476
- Publisher
- Springer
- Year
- 2012
- Tongue
- English
- Weight
- 923 KB
- Volume
- 23
- Category
- Article
- ISSN
- 1040-0400
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π SIMILAR VOLUMES
The phosphoraneiminato complexes [MnBr(NPEt 3 )] 4 (1) and [M 4 Br 5 {NP(NMe 2 ) 3 } 3 ] with M = Mn (2) and M = Co (3) are prepared by melting reactions from the anhydrous metal dibromides with the silylated phosphaneimines Me 3 SiNPR 3 (R = Et, NMe 2 ) in the presence of potassium fluoride. All co
The average magnetic susceptibility 0-2-100 K) and magnetisation (105-15500 Oe at 4.2 IQ of two perchlorato manganese(lII) porphyrins establish them to be high-spin, in contrast to the "anomalous" behaviour of analogous iron(M) porphyrins An explanation of the origin of the zero-field splitting in h
The phosphorane iminato ligand [NPRJ-, which is