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Magnetic properties and electronic structure of manganese(III) porphyrins

✍ Scribed by L.B. Dugad; D.V. Behere; V.R. Marathe; S. Mitra

Publisher: Elsevier Science
Year: 1984
Tongue: English
Weight: 391 KB
Volume: 104
Category: Article
ISSN: 0009-2614
DOI: 10.1016/0009-2614(84)80078-0

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✦ Synopsis

The average magnetic susceptibility 0-2-100 K) and magnetisation (105-15500 Oe at 4.2 IQ of two perchlorato manganese(lII) porphyrins establish them to be high-spin, in contrast to the "anomalous" behaviour of analogous iron(M) porphyrins An explanation of the origin of the zero-field splitting in high-spin man_@mese(III) porphyrins is presented.

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