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Manganese Oxydiacetate Complexes: Synthesis, Structure and Magnetic Properties

✍ Scribed by Abdessamad Grirrane; Antonio Pastor; Eleuterio Álvarez; Carlo Mealli; Andrea Ienco; Patrick Rosa; Francisco Montilla; Agustín Galindo

Publisher
John Wiley and Sons
Year
2004
Tongue
English
Weight
303 KB
Volume
2004
Category
Article
ISSN
1434-1948

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## Abstract Four cyanido‐bridged Mn^III^–Cr^I^ heterodimetallic complexes have been synthesized by the reactions of Mn^III^ Schiff‐base complexes with the [Cr(CN)~5~(NO)]^3–^ building block. X‐ray diffraction analysis reveals that [Mn(5‐Cl‐salen)(H~2~O)~2~][Mn~2~(5‐Cl‐salen)~2~(H~2~O)~1.5~Cr(CN)~5~