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Phosphoraneiminato Complexes of Manganese, Iron, and Cobalt with Heterocubane Structures

✍ Scribed by Riese, Ulrike; Faza, Naim; Harms, Klaus; Massa, Werner; Neumüller, Bernhard; Dehnicke, Kurt

Book ID
126551370
Publisher
Taylor and Francis Group
Year
1997
Tongue
English
Weight
279 KB
Volume
124
Category
Article
ISSN
1042-6507

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Phosphoraneiminato Complexes of Manganes
Phosphoraneiminato Complexes of Manganese and Cobalt with Heterocubane Structure
✍ Ulrike Riese; Naim Faza; Werner Massa; Klaus Harms; Thees Breyhan; Paul Knochel; 📂 Article 📅 1999 🏛 John Wiley and Sons 🌐 German ⚖ 135 KB

The phosphoraneiminato complexes [MnBr(NPEt 3 )] 4 (1) and [M 4 Br 5 {NP(NMe 2 ) 3 } 3 ] with M = Mn (2) and M = Co (3) are prepared by melting reactions from the anhydrous metal dibromides with the silylated phosphaneimines Me 3 SiNPR 3 (R = Et, NMe 2 ) in the presence of potassium fluoride. All co