Synthesis, Crystal Structure, and Spectroscopic Characterization of the Phosphorane Iminato Complexes [Cl2BNPCl2NPCl3]2 and [Br2BNPCl3]2.
โ Scribed by Britta Jaeschke; Martin Jansen
- Publisher
- John Wiley and Sons
- Year
- 2010
- Weight
- 32 KB
- Volume
- 33
- Category
- Article
- ISSN
- 0931-7597
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๐ SIMILAR VOLUMES
## IN MEMORIAM JEAN ROUXEL Diammine magnesium halides Mg(NH 3 ) 2 X 2 with X โซุโฌ Cl, Br, I have been prepared from magnesium metal and the corresponding ammonium halide in steel autoclaves at 3503C. Mg(NH 3 ) 2 Cl 2 crystallizes in the Cd (NH 3 ) 2 Cl 2 -structure type: Rietveld X-ray analysis, Cm
Diammine nickel(II) halides, Ni(NH 3 ) 2 X 2 (X โซุโฌ Cl, Br, I), were prepared by decomposition of the corresponding hexaammines at 1203C in dynamical vacuum. Their crystal structures are of the Cd(NH 3 ) 2 Cl 2 type (99 -type::, space group Cmmm, Z โซุโฌ 2): for Ni(NH 3 ) 2 Cl 2 , a โซุโฌ 8.019 A s , b