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Phosphabenzene–rhodium catalysts for the efficient hydroformylation of terminal and internal olefins

✍ Scribed by Breit, Bernhard; Winde, Roland; Harms, Klaus

Book ID
120011951
Publisher
Royal Society of Chemistry
Year
1997
Weight
62 KB
Volume
18
Category
Article
ISSN
1472-7781

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📜 SIMILAR VOLUMES

Hydroformylation of Internal Olefins to
Hydroformylation of Internal Olefins to Linear Aldehydes with Novel Rhodium Catalysts
✍ Lars A. van der Veen; Paul C. J. Kamer; Piet W. N. M. van Leeuwen 📂 Article 📅 1999 🏛 John Wiley and Sons 🌐 English ⚖ 105 KB 👁 2 views

Unprecedented high activities and selectivities were observed in the hydroformylation of internal octenes to linear products using rhodium catalysts with rigid diphosphane ligands. Dibenzophosphole 1 and a phenoxaphosphane analogue with bite angles of 120 and 119°, respectively, are suited for this.