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Supported aqueous-phase, rhodium hydroformylation catalysts II. Hydroformylation of linear, terminal and internal olefins

✍ Scribed by Juan P. Arhancet; Mark E. Davis; Brian E. Hanson


Book ID
113180207
Publisher
Elsevier Science
Year
1991
Tongue
English
Weight
423 KB
Volume
129
Category
Article
ISSN
0021-9517

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Hydroformylation of Internal Olefins to
✍ Lars A. van der Veen; Paul C. J. Kamer; Piet W. N. M. van Leeuwen 📂 Article 📅 1999 🏛 John Wiley and Sons 🌐 English ⚖ 105 KB 👁 2 views

Unprecedented high activities and selectivities were observed in the hydroformylation of internal octenes to linear products using rhodium catalysts with rigid diphosphane ligands. Dibenzophosphole 1 and a phenoxaphosphane analogue with bite angles of 120 and 119°, respectively, are suited for this.