✦ LIBER ✦

Hydroformylation of Internal Olefins to Linear Aldehydes with Novel Rhodium Catalysts

✍ Scribed by Lars A. van der Veen; Paul C. J. Kamer; Piet W. N. M. van Leeuwen

Publisher: John Wiley and Sons
Year: 1999
Tongue: English
Weight: 105 KB
Volume: 38
Category: Article
ISSN: 0044-8249
DOI: 10.1002/(sici)1521-3773(19990201)38:3<336::aid-anie336>3.0.co;2-p

No coin nor oath required. For personal study only.

✦ Synopsis

Unprecedented high activities and selectivities were observed in the hydroformylation of internal octenes to linear products using rhodium catalysts with rigid diphosphane ligands. Dibenzophosphole 1 and a phenoxaphosphane analogue with bite angles of 120 and 119°, respectively, are suited for this.

📜 SIMILAR VOLUMES

Highly Selective Catalyst Systems for th

Highly Selective Catalyst Systems for the Hydroformylation of Internal Olefins to Linear Aldehydes

✍ Holger Klein; Ralf Jackstell; Klaus-Diether Wiese; Cornelia Borgmann; Matthias B 📂 Article 📅 2001 🏛 John Wiley and Sons 🌐 English ⚖ 92 KB 👁 2 views

ChemInform Abstract: Highly Selective Ca

ChemInform Abstract: Highly Selective Catalyst Systems for the Hydroformylation of Internal Olefins to Linear Aldehydes.

✍ Holger Klein; Ralf Jackstell; Klaus-Diether Wiese; Cornelia Borgmann; Matthias B 📂 Article 📅 2010 🏛 John Wiley and Sons ⚖ 32 KB 👁 2 views

Rhodium-Catalyzed Hydroformylation of In

Rhodium-Catalyzed Hydroformylation of Internal Alkynes to α,β-Unsaturated Aldehydes

✍ Dr. John R. Johnson; Dr. Gregory D. Cuny; Prof. Dr. Stephen L. Buchwald 📂 Article 📅 1995 🏛 John Wiley and Sons 🌐 English ⚖ 250 KB

ChemInform Abstract: Phosphabenzene—Rhod

ChemInform Abstract: Phosphabenzene—Rhodium Catalysts for the Efficient Hydroformylation of Terminal and Internal Olefins.

✍ B. BREIT; R. WINDE; K. HARMS 📂 Article 📅 2010 🏛 John Wiley and Sons ⚖ 33 KB 👁 1 views

One-Pot Carbon Monoxide-Free Hydroformyl

One-Pot Carbon Monoxide-Free Hydroformylation of Internal Olefins to Terminal Aldehydes

✍ David R. Edwards; Cathleen M. Crudden; Katherine Yam 📂 Article 📅 2005 🏛 John Wiley and Sons 🌐 English ⚖ 74 KB 👁 1 views

Rhodium Complexes Non-Covalently Bound t

Rhodium Complexes Non-Covalently Bound to Cyclodextrins: Novel Water-Soluble Supramolecular Catalysts for the Biphasic Hydroformylation of Higher Olefins

✍ Benoît Sueur; Loïc Leclercq; Mathieu Sauthier; Yves Castanet; André Mortreux; He 📂 Article 📅 2005 🏛 John Wiley and Sons 🌐 English ⚖ 176 KB