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Highly Selective Catalyst Systems for the Hydroformylation of Internal Olefins to Linear Aldehydes

✍ Scribed by Holger Klein; Ralf Jackstell; Klaus-Diether Wiese; Cornelia Borgmann; Matthias Beller

Publisher
John Wiley and Sons
Year
2001
Tongue
English
Weight
92 KB
Volume
40
Category
Article
ISSN
0044-8249

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πŸ“œ SIMILAR VOLUMES

Hydroformylation of Internal Olefins to
Hydroformylation of Internal Olefins to Linear Aldehydes with Novel Rhodium Catalysts
✍ Lars A. van der Veen; Paul C. J. Kamer; Piet W. N. M. van Leeuwen πŸ“‚ Article πŸ“… 1999 πŸ› John Wiley and Sons 🌐 English βš– 105 KB πŸ‘ 1 views

Unprecedented high activities and selectivities were observed in the hydroformylation of internal octenes to linear products using rhodium catalysts with rigid diphosphane ligands. Dibenzophosphole 1 and a phenoxaphosphane analogue with bite angles of 120 and 119Β°, respectively, are suited for this.