Unprecedented high activities and selectivities were observed in the hydroformylation of internal octenes to linear products using rhodium catalysts with rigid diphosphane ligands. Dibenzophosphole 1 and a phenoxaphosphane analogue with bite angles of 120 and 119°, respectively, are suited for this.
✦ LIBER ✦
Rhodium-Catalyzed Hydroformylation of Internal Alkynes to α,β-Unsaturated Aldehydes
✍ Scribed by Dr. John R. Johnson; Dr. Gregory D. Cuny; Prof. Dr. Stephen L. Buchwald
- Publisher
- John Wiley and Sons
- Year
- 1995
- Tongue
- English
- Weight
- 250 KB
- Volume
- 34
- Category
- Article
- ISSN
- 0044-8249
No coin nor oath required. For personal study only.
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