Low pressure, highly active rhodium catalyst for the homogeneous hydroformylation of olefins
✍ Scribed by A.M. Trzeciak; J.J. Ziółkowski
- Publisher
- Elsevier Science
- Year
- 1986
- Weight
- 422 KB
- Volume
- 34
- Category
- Article
- ISSN
- 0304-5102
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## Abstract The hydroformylation of olefins over rhodium catalysts, with phosphorus ligands added in situ, has been studied under atmospheric pressure. In the case of the Rh~4~(CO)~12~ cluster, the phosphine‐modified catalyst exhibits very high activity, but there is a decay of catalyst activity wi
The first synthesis of a water-soluble cationic sugar-substituted arene rhodium complex has been described. The w Ž . x water-soluble cationic rhodium complex was synthesized by the reaction of an ethanol solution of Rh COD Cl with 2 AgBF and then with phenyl-b-D-glucopyranoside. This water-soluble