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New rhodium complexes as low pressure hydroformylation catalysts: effect of ligand on catalyst activity and selectivity

✍ Scribed by Helga Janecko; Anna M. Trzeciak; Jiózef J. Ziółkowski


Publisher
Elsevier Science
Year
1984
Weight
459 KB
Volume
26
Category
Article
ISSN
0304-5102

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Effect of phosphorus ligands on the hydr
✍ Wanzhi Chen; Shijian Liao; Yun Xu 📂 Article 📅 1992 🏛 John Wiley and Sons 🌐 English ⚖ 525 KB

## Abstract The hydroformylation of olefins over rhodium catalysts, with phosphorus ligands added in situ, has been studied under atmospheric pressure. In the case of the Rh~4~(CO)~12~ cluster, the phosphine‐modified catalyst exhibits very high activity, but there is a decay of catalyst activity wi