## Abstract The 1βmethoxyβ2β(supermesitylphosphanylidenemethyl)βbenzene ligand (**1**) was prepared by reacting the phosphaβWittig reagent [Mes\*Pο£ΎPMe~3~] with oβmethoxybenzaldehyde. Reaction of 1 with one equivalent of the [Pd(allyl)Cl]~2~ dimer in the presence of Ag(OTf) affords a neutral complex
Phosphaalkenes Palladium(II) Complexes in the Suzuki and Sonogashira Cross-Coupling Reactions.
β Scribed by Bernard Deschamps; Xavier Le Goff; Louis Ricard; Pascal Le Floch
- Book ID
- 102007662
- Publisher
- John Wiley and Sons
- Year
- 2007
- Weight
- 22 KB
- Volume
- 38
- Category
- Article
- ISSN
- 0931-7597
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## Abstract A new palladium-bidentate complex [m-C6H4(CH2ImMe)2(PdCl2)] (III) was prepared in two steps. In the first step, [m-C6H4(CH2ImMeAgCl)2] (II) (Im = imidazole moiety) was obtained by reacting imidazolium salt [m-C6H4(CH2ImMe)2]Cl2 (I) (prepared by quaternisation of Nmethylimidazole with 1,