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New acyclic aminocarbene palladium(ii) complexes as convenient catalysts for the Sonogashira and Suzuki cross-coupling

✍ Scribed by Valishina, E. A.; Buslaeva, T. M.; Luzyanin, K. V.


Book ID
125368767
Publisher
Springer
Year
2013
Tongue
English
Weight
185 KB
Volume
62
Category
Article
ISSN
1573-9171

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Phosphaalkenes palladium(II) complexes i
✍ Bernard Deschamps; Xavier Le Goff; Louis Ricard; Pascal Le Floch πŸ“‚ Article πŸ“… 2007 πŸ› John Wiley and Sons 🌐 English βš– 359 KB

## Abstract The 1‐methoxy‐2‐(supermesitylphosphanylidenemethyl)‐benzene ligand (**1**) was prepared by reacting the phospha‐Wittig reagent [Mes\*Pο£ΎPMe~3~] with o‐methoxybenzaldehyde. Reaction of 1 with one equivalent of the [Pd(allyl)Cl]~2~ dimer in the presence of Ag(OTf) affords a neutral complex