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Catalytic activity of palladium(II) diaminocarbene complexes in the Sonogashira and Suzuki reactions

✍ Scribed by V. N. Mikhailov, E. A. Savicheva, V. N. Sorokoumov…

Book ID
120771862
Publisher
SP MAIK Nauka/Interperiodica
Year
2013
Tongue
English
Weight
183 KB
Volume
49
Category
Article
ISSN
1070-4280

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Phosphaalkenes palladium(II) complexes in the suzuki and sonogashira cross-coupling reactions
✍ Bernard Deschamps; Xavier Le Goff; Louis Ricard; Pascal Le Floch 📂 Article 📅 2007 🏛 John Wiley and Sons 🌐 English ⚖ 359 KB

## Abstract The 1‐methoxy‐2‐(supermesitylphosphanylidenemethyl)‐benzene ligand (**1**) was prepared by reacting the phospha‐Wittig reagent [Mes\*PPMe~3~] with o‐methoxybenzaldehyde. Reaction of 1 with one equivalent of the [Pd(allyl)Cl]~2~ dimer in the presence of Ag(OTf) affords a neutral complex