All of the stereoisomers of 10,14-dimethyloctadec-1-ene (1), (Lyonetia prunifoliella), were synthesized by starting from the enantiomers of citronellol (4) and methyl 3-hydroxy-2-5,9-dimethyloctadecane (2) and 5,9-dimethylheptadecane (3), the sex pheromone components of the apple leafminer methylpro
Pheromone synthesis, CXXIX. Synthesis of the (5S,9S)-isomers of 5,9-Dimethylheptadecane and 5,9-dimethyloctadecane, the major and the minor components of the sex pheromone ofLeucoptera malifoliella costa
✍ Scribed by Mori, Kenji ;Wu, Jiang
- Publisher
- John Wiley and Sons
- Year
- 1991
- Tongue
- English
- Weight
- 470 KB
- Volume
- 1991
- Category
- Article
- ISSN
- 0947-3440
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✦ Synopsis
Abstract
The synthesis of (5__S__,9__S__)‐5,9‐dimethylheptadecane (1) as well as that of (5__S__,9__S__)‐5,9‐dimethyloctadecane (2) has been achieved by starting from methyl (R)‐3‐hydroxy‐2‐methylpropanoate (3a) and (S)‐citronellal (7).
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