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Pheromone Synthesis, CLXXIV. Synthesis of (5R,11S)-5,11-Dimethylheptadecane and (S)-2,5-Dimethylheptadecane, the Major and the Minor Components of the Sex Pheromone of the Geometrid Moth, Lambdina fiscellaria lugubrosa

✍ Scribed by Mori, Kenji ;Horikiri, Hiromasa

Publisher
John Wiley and Sons
Year
2006
Tongue
English
Weight
505 KB
Volume
1996
Category
Article
ISSN
0947-3440

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✦ Synopsis

Abstract

(5__R__,11__S__)‐5,11‐Dimethylheptadecane (1), the major component of the female‐produced sex pheromone of the western hemlock looper (Lambdina fiscellaria lugubrosa), was synthesized by starting from the enantiomers of methyl 3‐hydroxy‐2‐methylpropanoate (3). (S)‐2,5‐Dimethylheptadecane (2), the minor and synergistic component of the pheromone, was also synthesized by starting from (S)‐citronellol (4).

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