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ChemInform Abstract: Pheromone Synthesis. Part 200. Synthesis of (S)-9-Methylgermacrene-B, the Male-Produced Sex Pheromone of the Sandfly Lutzomyia longipalpis from Lapinha, Brazil, and Its (R)-Isomer.

✍ Scribed by Satoshi Kurosawa; Kenji Mori

Publisher: John Wiley and Sons
Year: 2010
Weight: 28 KB
Volume: 31
Category: Article
ISSN: 0931-7597
DOI: 10.1002/chin.200020212

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Synthesis of (S)-9-Methylgermacrene-B, t

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Both the enantiomers of 9-methylgermacrene-B (1) were synthesized from the enantiomers of methyl 3-hydroxy-2methylpropanoate (2). The male-produced sex pheromone of

ChemInform Abstract: Pheromone Synthesis

ChemInform Abstract: Pheromone Synthesis. Part 196. Synthesis of Germacrene-B and Its Extension to the Synthesis of (.+-.)-9-Methylgermacrene-B, the Racemate of the Male-Produced Sex Pheromone of the Sandfly Lutzomyia longipalpis from Lapinha, Brazil.

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Synthesis of Germacrene-B and Its Extension to the Synthesis of (±)-9-Methylgermacrene-B, the Racemate of the Male-Produced Sex Pheromone of the Sandfly Lutzomyia longipalpis from Lapinha, Brazil

✍ Shin-etsu Muto; Yutaka Nishimura; Kenji Mori 📂 Article 📅 1999 🏛 John Wiley and Sons 🌐 English ⚖ 235 KB 👁 1 views

## Both germacrene-B (2) and 9-methylgermacrene-B [(±)-1] shown to be the racemate of the male-produced sex pheromone of the sandfly Lutzomyia longipalpis from were synthesized by employing cyclization reactions [8 Ǟ 9 and (±)-20 Ǟ (±)-21] as the key steps. The latter [(±)-1] was Lapinha, Brazil.

ChemInform Abstract: 9-Methylgermacrene-

ChemInform Abstract: 9-Methylgermacrene-B is Confirmed as the Sex Pheromone of the Sandfly Lutzomyia longipalpis from Lapinha, Brazil, and the Absolute Stereochemistry Defined as S.

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ChemInform Abstract: Pheromone Synthesis

ChemInform Abstract: Pheromone Synthesis. Part 195. Synthesis of (1R*,3R*,7R*)-3-Methyl-α-himachalene, the Racemate of the Male-Produced Sex Pheromone of the Sandfly Lutzomyia longipalpis from Jacobina, Brazil.

✍ Satoshi Sano; Kenji Mori 📂 Article 📅 2010 🏛 John Wiley and Sons ⚖ 32 KB 👁 1 views

Synthesis of (1R*,3R*,7R*)-3-Methyl-α-hi

Synthesis of (1R*,3R*,7R*)-3-Methyl-α-himachalene, the Racemate of the Male-Produced Sex Pheromone of the Sandfly Lutzomyia longipalpis from Jacobina, Brazil

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Four stereoisomers (1a-d) of (±)-3-methyl-α-himachalene produced sex pheromone of the sandfly Lutzomyia longipalpis was shown to possess the structure and relative were synthesized by employing the intramolecular Diels-Alder reaction of (±)-14 to (±)-18 as the key-step. The male-configuration as dep