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ChemInform Abstract: Pheromone Synthesis. Part 195. Synthesis of (1R*,3R*,7R*)-3-Methyl-α-himachalene, the Racemate of the Male-Produced Sex Pheromone of the Sandfly Lutzomyia longipalpis from Jacobina, Brazil.

✍ Scribed by Satoshi Sano; Kenji Mori


Publisher
John Wiley and Sons
Year
2010
Weight
32 KB
Volume
30
Category
Article
ISSN
0931-7597

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Synthesis of (1R*,3R*,7R*)-3-Methyl-α-hi
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Four stereoisomers (1a-d) of (±)-3-methyl-α-himachalene produced sex pheromone of the sandfly Lutzomyia longipalpis was shown to possess the structure and relative were synthesized by employing the intramolecular Diels-Alder reaction of (±)-14 to (±)-18 as the key-step. The male-configuration as dep

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