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ChemInform Abstract: 3-Methyl-α-himachalene is Confirmed, and the Relative Stereochemistry Defined, by Synthesis as the Sex Pheromone of the Sandfly Lutzomyia longipalpis from Jacobina, Brazil.

✍ Scribed by J. Gordon C. Hamilton; Antony M. Hooper; Kenji Mori; John A. Pickett; Satoshi Sano

Publisher
John Wiley and Sons
Year
2010
Weight
35 KB
Volume
30
Category
Article
ISSN
0931-7597

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✦ Synopsis

Abstract

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Synthesis of (1R*,3R*,7R*)-3-Methyl-α-himachalene, the Racemate of the Male-Produced Sex Pheromone of the Sandfly Lutzomyia longipalpis from Jacobina, Brazil
✍ Satoshi Sano; Kenji Mori 📂 Article 📅 1999 🏛 John Wiley and Sons 🌐 English ⚖ 337 KB

Four stereoisomers (1a-d) of (±)-3-methyl-α-himachalene produced sex pheromone of the sandfly Lutzomyia longipalpis was shown to possess the structure and relative were synthesized by employing the intramolecular Diels-Alder reaction of (±)-14 to (±)-18 as the key-step. The male-configuration as dep