Both the enantiomers of 9-methylgermacrene-B (1) were synthesized from the enantiomers of methyl 3-hydroxy-2methylpropanoate (2). The male-produced sex pheromone of
ChemInform Abstract: 9-Methylgermacrene-B is Confirmed as the Sex Pheromone of the Sandfly Lutzomyia longipalpis from Lapinha, Brazil, and the Absolute Stereochemistry Defined as S.
β Scribed by J. Gordon C. Hamilton; Antony M. Hooper; Helen C. Ibbotson; Satoshi Kurosawa; Kenji Mori; Shin-etsu Muto; John A. Pickett
- Publisher
- John Wiley and Sons
- Year
- 2010
- Weight
- 30 KB
- Volume
- 31
- Category
- Article
- ISSN
- 0931-7597
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## Both germacrene-B (2) and 9-methylgermacrene-B [(Β±)-1] shown to be the racemate of the male-produced sex pheromone of the sandfly Lutzomyia longipalpis from were synthesized by employing cyclization reactions [8 Η 9 and (Β±)-20 Η (Β±)-21] as the key steps. The latter [(Β±)-1] was Lapinha, Brazil.