## Abstract (4__R__,5__R__,6__S__,7__E__,9__E__)โ4,6,8โTrimethylโ7,9โundecadienโ5โol (1) and its antipode 1โฒ, the female specific compound of the woodroach __Cryptocercus punctulatus__, were synthesized by starting from methyl (__R__)โ3โhydroxyโ2โmethylpropanoate (C).
Pheromone Synthesis, CLXIV. Synthesis of (2S, 6Z)-6,8-Nonadien-2-ol, a Pheromone Component of the LeafminerNepticula malella, and Its Antipode
โ Scribed by Mori, Kenji ;Ogita, Haruhisa
- Publisher
- John Wiley and Sons
- Year
- 1994
- Tongue
- English
- Weight
- 491 KB
- Volume
- 1994
- Category
- Article
- ISSN
- 0947-3440
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โฆ Synopsis
Abstract
Both the enantiomers of (Z)โ6,8โnonadienโ2โol were synthesized via lipaseโcatalyzed asymmetric hydrolysis of the acetate of its racemate, which was prepared from ethyl levulinate.
๐ SIMILAR VOLUMES
The enantioselective syntheses of two stereoisomers, (2R,6S,10S) and (2S,6S,10S), of methyl 2,6,10-trimethyldodecanote, out of eight possible isomers, are described , employing the stereoselective hydroboration of (-)-isopulegol (2) and (+)-neo-isopulegol (2a) as the key reaction.
## Abstract The kinetic separation of the diastereomeric title alcohols is accomplished by their acylation with succinic anhydride in the presence of lipase Amano PS.