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ChemInform Abstract: Chemoenzymatic Synthesis of the Aggregation Pheromones (S)-2-Methyl-4-octanol and (4S,2E)-6-Methyl-2-hepten-4-ol.

โœ Scribed by Francisco A. Marques; Ademir Zimmermann; Carlos E. Delay; Beatriz Helena L. N. Sales Maia


Publisher
John Wiley and Sons
Year
2008
Weight
26 KB
Volume
39
Category
Article
ISSN
0931-7597

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Chemoenzymatic Synthesis of (4S)- and (4
โœ Virgil Helaine; Jean Bolte ๐Ÿ“‚ Article ๐Ÿ“… 1999 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 229 KB ๐Ÿ‘ 2 views

Alkylation of dimethyl 2,2-dimethoxyglutarate followed by transamination provides an efficient synthesis of (4S)-and (4R)-4-methyl-L-glutamic acids which are very useful for enzymatic resolution afforded (4S)-and (4R)-4-methyl-2oxoglutaric acid in an enantiomerically pure form. The characterisation