𝔖 Bobbio Scriptorium
✦   LIBER   ✦

Pheromone syntheses: A tropical approach. Enantioselective synthesis of the (2R,6S,10S) and (2S,6S,10S) isomers of methyl 2,6,10-trimethyldodecanoate

✍ Scribed by J.Tércio B. Ferreira; Paulo H.G. Zarbin

Publisher
Elsevier Science
Year
1996
Tongue
English
Weight
622 KB
Volume
4
Category
Article
ISSN
0968-0896

No coin nor oath required. For personal study only.

✦ Synopsis

The enantioselective syntheses of two stereoisomers, (2R,6S,10S) and (2S,6S,10S), of methyl 2,6,10-trimethyldodecanote, out of eight possible isomers, are described , employing the stereoselective hydroboration of (-)-isopulegol (2) and (+)-neo-isopulegol (2a) as the key reaction.

📜 SIMILAR VOLUMES

Synthesis of (1S,2S,6S,10R)- and (1S,2R,
Synthesis of (1S,2S,6S,10R)- and (1S,2R,6R,10R)-1,2,6,10-Tetramethyldodecyl Propanoate, the Components of the Sex Pheromone of the Pine Sawfly, Microdiprion pallipes
✍ Yoshihide Nakamura; Kenji Mori 📂 Article 📅 1999 🏛 John Wiley and Sons 🌐 English ⚖ 236 KB 👁 1 views

butoxycarbonyl-2-methylpropanoic acid (D) and (2R,6S)-7acetoxy-2,6-dimethyl-1-heptanol (G), by employing lipase-dodecyl propanoate (1 and 2), the components of the pheromone of Microdiprion pallipes, were synthesized from catalyzed kinetic resolution in a later step. two chiral and nonracemic buildi

ChemInform Abstract: Chemoenzymatic Synt
ChemInform Abstract: Chemoenzymatic Synthesis of (2R,6R,10R)-6,10,14-Trimethylpentadecan-2-ol, Sex Pheromone of Rice Moth (Corcyra cephalonica), and of Its (2S,6R,10R)-Diastereomer.
✍ R. V. Shafikov; A. Yu. Spivak; V. N. Odinokov 📂 Article 📅 2011 🏛 John Wiley and Sons ⚖ 18 KB 👁 1 views

## Abstract The kinetic separation of the diastereomeric title alcohols is accomplished by their acylation with succinic anhydride in the presence of lipase Amano PS.