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ChemInform Abstract: Chemoenzymatic Synthesis of (2R,6R,10R)-6,10,14-Trimethylpentadecan-2-ol, Sex Pheromone of Rice Moth (Corcyra cephalonica), and of Its (2S,6R,10R)-Diastereomer.

โœ Scribed by R. V. Shafikov; A. Yu. Spivak; V. N. Odinokov

Publisher
John Wiley and Sons
Year
2011
Weight
18 KB
Volume
42
Category
Article
ISSN
0931-7597

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โœฆ Synopsis

Abstract

The kinetic separation of the diastereomeric title alcohols is accomplished by their acylation with succinic anhydride in the presence of lipase Amano PS.

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Synthesis of (1S,2S,6S,10R)- and (1S,2R,
Synthesis of (1S,2S,6S,10R)- and (1S,2R,6R,10R)-1,2,6,10-Tetramethyldodecyl Propanoate, the Components of the Sex Pheromone of the Pine Sawfly, Microdiprion pallipes
โœ Yoshihide Nakamura; Kenji Mori ๐Ÿ“‚ Article ๐Ÿ“… 1999 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 236 KB ๐Ÿ‘ 1 views

butoxycarbonyl-2-methylpropanoic acid (D) and (2R,6S)-7acetoxy-2,6-dimethyl-1-heptanol (G), by employing lipase-dodecyl propanoate (1 and 2), the components of the pheromone of Microdiprion pallipes, were synthesized from catalyzed kinetic resolution in a later step. two chiral and nonracemic buildi