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[Ph4P]2[Ni3N8S8], a Novel Trinuclear Complex with Sulfur-Nitrogen Ligands

✍ Scribed by Prof. Dr. Johannes Weiss

Publisher
John Wiley and Sons
Year
1984
Tongue
English
Weight
133 KB
Volume
23
Category
Article
ISSN
0044-8249

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✦ Synopsis

Alkalis react with the violet, planar complex [Ni(HN,S,),] 1 to afford brown and red salts of the anions [Ni(HNzSz)(NzSz)]Q and [Ni(N2Sz)z]2Q 2, respectively"'. In turn, 2 can also act as a bidentate ligand in complexes.

Thus with, e.g., Ni'@ the anion 3 is formed, a trinuclear complex in which two moieties of 2 are linked to each other via a further nickel atom.

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