[Ph4P]2[Ni3N8S8], a Novel Trinuclear Com
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Prof. Dr. Johannes Weiss
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Article
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1984
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John Wiley and Sons
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English
β 133 KB
Alkalis react with the violet, planar complex [Ni(HN,S,),] 1 to afford brown and red salts of the anions [Ni(HNzSz)(NzSz)]Q and [Ni(N2Sz)z]2Q 2, respectively"'. In turn, 2 can also act as a bidentate ligand in complexes. Thus with, e.g., Ni'@ the anion 3 is formed, a trinuclear complex in which two