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A Trinuclear Palladium(II) Complex with Bridging 2-Hydroxyacetophenone N4-Ethylthiosemicarbazone Ligands − An Unusual Dimethylformamide Promoted Deprotonation and Aggregation

✍ Scribed by Dimitra Kovala-Demertzi; Nikolaos Kourkoumelis; Douglas X. West; Jesús Valdés-Martínez; Simon Hernández-Ortega


Publisher
John Wiley and Sons
Year
1998
Tongue
English
Weight
454 KB
Volume
1998
Category
Article
ISSN
1434-1948

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✦ Synopsis


The X-ray crystal structure of a palladium(II) complex of 2hydroxyacetophenone N 4 -ethylthiosemicarbazone (H 2 Ap4E) shows it to be a triangular, trinuclear complex with bridging thiosemicarbazonato sulfur atoms. This species can be for-