Pentacarbonyl[diphenyl(perfluorovinyl)phosphine]molybdenum(0)
✍ Scribed by Peters, R. Gregory ;Palcic, Jason D. ;Baughman, Russell G.
- Publisher
- International Union of Crystallography
- Year
- 2003
- Tongue
- English
- Weight
- 204 KB
- Volume
- 59
- Category
- Article
- ISSN
- 1600-5368
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📜 SIMILAR VOLUMES
In the title compound, [Fe(C 5 H 5 )(C 4 H 9 NSi)(C 18 H 15 P)(CO)]-(CF 3 SO 3 )Á0.5CH 2 Cl 2 , the Fe II atom is coordinated by carbonyl, triphenylphosphine, trimethylsilyl isocyanide and cyclopentadienyl ligands in a typical piano-stool structure. The Fe-C-N-Si arrangement is almost linear and the
The title compound, (-(SCH 2 ) 2 CH 2 )Fe(CO) 3 Fe(CO) 2 P-(C 6 H 5 ) 2 NHCH 2 CH 2 CH 3 , has been prepared and characterized as a a model substance for a class of enzymes known as hydrogenases.
Single-crystal X-ray study T = 298 K Mean '(C±C) = 0.008 A Ê R factor = 0.038 wR factor = 0.113 Data-to-parameter ratio = 7.3 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.