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trans-Tri­carbonylbis­[di­phenyl­(benzoyl­methyl)­phosphine]­iron(0)

✍ Scribed by Da-Jun, Cui ;Xianshun, Zeng ;Xuebing, Leng ;Fengbo, Xu ;Zhengzhi, Zhang

Publisher
International Union of Crystallography
Year
2003
Tongue
English
Weight
168 KB
Volume
59
Category
Article
ISSN
1600-5368

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✍ Nakazawa, Hiroshi ;Itazaki, Masumi ;Owaribe, Mari 📂 Article 📅 2005 🏛 International Union of Crystallography 🌐 English ⚖ 119 KB

In the title compound, [Fe(C 5 H 5 )(C 4 H 9 NSi)(C 18 H 15 P)(CO)]-(CF 3 SO 3 )Á0.5CH 2 Cl 2 , the Fe II atom is coordinated by carbonyl, triphenylphosphine, trimethylsilyl isocyanide and cyclopentadienyl ligands in a typical piano-stool structure. The Fe-C-N-Si arrangement is almost linear and the