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Palladium(0) catalysed allylation reactions with racemic and enantiomerically pure allylic sulfoximines

โœ Scribed by Stephen G. Pyne; Gareth O'Meara; Dorothy M. David

Publisher
Elsevier Science
Year
1997
Tongue
French
Weight
195 KB
Volume
38
Category
Article
ISSN
0040-4039

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Palladium (0) catalysed rearrangements o
Palladium (0) catalysed rearrangements of allylic sulfoximines to allyl sulfinimidic acid esters and optically active N-Cbz protected ฮณ-amino-enones
โœ Stephen G. Pyne; Dorothy M. David; Zemin Dong ๐Ÿ“‚ Article ๐Ÿ“… 1998 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 236 KB

N-Tosyl allylic sulfoximines undergo rearrangement to allyl sulfinimidic acid esters in the presence of bidentate chiral ligands while N-Cbz allylic sulfoximines give optically active N-Cbz protected T-aminoenones.