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Palladium catalysed allylic substitution reactions of prochiral and racemic allyl acetates

✍ Scribed by Graham J Dawson; Jonathan MJ William; Steven J Coote


Publisher
Elsevier Science
Year
1995
Tongue
French
Weight
117 KB
Volume
36
Category
Article
ISSN
0040-4039

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Palladium-catalysed synthesis of allyl a
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Allyl acetates were synthesised from allenes utilising methodology based on the general reactivity of p-allyl palladium intermediates which participate efficiently in transformations involving nucleophiles. Reactions of allenes and aryl iodides in the presence of AcONa and Pd(OAc) 2 /PPh 3 as the c