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Palladium-catalyzed synthesis of allenes.

✍ Scribed by Tuyêt Jeffery-Luong; Gérard Linstrumelle

Book ID
104212711
Publisher
Elsevier Science
Year
1980
Tongue
French
Weight
96 KB
Volume
21
Category
Article
ISSN
0040-4039

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✦ Synopsis

Substituted allenes are selectively obtained in good yields from the reaction of Grignard reagents with propargylic or allenic halides in the presence of catalytic amounts of palladium chloride, triphenylphosphine and diisobutyl aluminum hydride, in

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The authors gratefully acknowledge the "Region RhBne-Alpes" for its financial support. REFERENCES a) WALSH,C. ; Tetrahedron, 1982, 2 , 871. b) ANGST,C.

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