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Palladium-Catalyzed Cocyclotrimerization of Allenes with Arynes: Selective Synthesis of Phenanthrenes

✍ Scribed by Liu, Yi-Lin; Liang, Yun; Pi, Shao-Feng; Huang, Xiao-Cheng; Li, Jin-Heng


Book ID
120812127
Publisher
American Chemical Society
Year
2009
Tongue
English
Weight
150 KB
Volume
74
Category
Article
ISSN
0022-3263

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Palladium-catalyzed synthesis of allenes
✍ TuyΓͺt Jeffery-Luong; GΓ©rard Linstrumelle πŸ“‚ Article πŸ“… 1980 πŸ› Elsevier Science 🌐 French βš– 96 KB

Substituted allenes are selectively obtained in good yields from the reaction of Grignard reagents with propargylic or allenic halides in the presence of catalytic amounts of palladium chloride, triphenylphosphine and diisobutyl aluminum hydride, in