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Palladium-catalyzed synthesis of dienic α-amino acids from allenes

✍ Scribed by Nina Kopola; Béatrice Friess; Bernard Cazes; Jacques Gore


Publisher
Elsevier Science
Year
1989
Tongue
French
Weight
212 KB
Volume
30
Category
Article
ISSN
0040-4039

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✦ Synopsis


The authors gratefully acknowledge the "Region RhBne-Alpes" for its financial support. REFERENCES a) WALSH,C. ; Tetrahedron, 1982, 2 , 871. b) ANGST,C.


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Palladium-catalyzed reaction of N-arylsulfonyl-l-alkyl-3,4-dienylamines with an aryl iodide in the presence of potassium carbonate in DMF at around 70°C affords most predominantly the 2,4-cis-disubstituted azacyclobutanes bearing an aryl group on the double bond in good yields.