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Palladium-catalyzed regio- and stereoselective synthesis of N-protected 2,4-dialkylated azacyclobutanes from amino allenes

✍ Scribed by Miyuki Anzai; Ayako Toda; Hiroaki Ohno; Yoshiji Takemoto; Nobutaka Fujii; Toshiro Ibuka

Publisher: Elsevier Science
Year: 1999
Tongue: French
Weight: 275 KB
Volume: 40
Category: Article
ISSN: 0040-4039
DOI: 10.1016/s0040-4039(99)01517-8

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✦ Synopsis

Palladium-catalyzed reaction of N-arylsulfonyl-l-alkyl-3,4-dienylamines with an aryl iodide in the presence of potassium carbonate in DMF at around 70°C affords most predominantly the 2,4-cis-disubstituted azacyclobutanes bearing an aryl group on the double bond in good yields.

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