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Palladium-Catalyzed One-Step Synthesis of Isoindole-1,3-diones by Carbonylative Cyclization of o -Halobenzoates and Primary Amines

✍ Scribed by Worlikar, Shilpa A.; Larock, Richard C.

Book ID
126310842
Publisher
American Chemical Society
Year
2008
Tongue
English
Weight
199 KB
Volume
73
Category
Article
ISSN
0022-3263

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## Abstract A new carbon monoxide‐free, solvent‐free, single step protocol for the synthesis of isoindole‐1,3‐diones from __o__‐haloarenes using palladium acetate and xantphos catalysis is reported. The wider applicability of this protocol for several types of __o__‐iodoarenes and a few __o__‐bromo