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Palladium-catalyzed synthesis of 3-(alkylamino)isoindolin-1-ones by carbonylative cyclization of 2-bromobenzaldehyde with primary amines

✍ Scribed by Chan Sik Cho; Li Hong Jiang; Dong Yub Lee; Sang Chul Shim; Hyung Soo Lee; Sung-Dong Cho

Publisher
Journal of Heterocyclic Chemistry
Year
1997
Tongue
English
Weight
263 KB
Volume
34
Category
Article
ISSN
0022-152X

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✦ Synopsis

Abstract

2‐Bromobenzaldehyde reacts with an excess of primary amines under a carbon monoxide in the presence of a catalytic amount of bis(triphenylphosphine)palladium(II) chloride together with triethylamine to give the corresponding 3‐(alkylamino)isoindolin‐1‐ones in good yields.

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