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Palladium-catalyzed hydrocarbonation of methyleneaziridines with carbon pronucleophiles

โœ Scribed by Byoung Ho Oh; Itaru Nakamura; Yoshinori Yamamoto

Book ID
104252531
Publisher
Elsevier Science
Year
2002
Tongue
French
Weight
171 KB
Volume
43
Category
Article
ISSN
0040-4039

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โœฆ Synopsis

The reaction of methyleneaziridine 1 with carbon pronucleophiles (2, H-CR 3 ) proceeds smoothly in the presence of a palladium catalyst affording the corresponding hydrocarbonation products 5 in good to high yield.

๐Ÿ“œ SIMILAR VOLUMES

Inter- and intramolecular palladium-cata
Inter- and intramolecular palladium-catalyzed hydrocarbonation of methylenecyclopropanes with carbon pronucleophiles
โœ Naofumi Tsukada; Akinori Shibuya; Itaru Nakamura; Haruo Kitahara; Yoshinori Yama ๐Ÿ“‚ Article ๐Ÿ“… 1999 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 553 KB

The inter-and intrarnolecular additions of pronucleophiles to methylenecyclopropanes proceeded smoothly in the presence of catalytic amounts of Pd(PPh3) 4, affording hydrocarbonation products in good to high yields. The ring opening of methylenecyclopropanes mainly occurred at the distal position to