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ChemInform Abstract: Inter- and Intramolecular Palladium-Catalyzed Hydrocarbonation of Methylenecyclopropanes with Carbon Pronucleophiles.

✍ Scribed by Naofumi Tsukada; Akinori Shibuya; Itaru Nakamura; Haruo Kitahara; Yoshinori Yamamoto


Publisher
John Wiley and Sons
Year
2010
Weight
36 KB
Volume
30
Category
Article
ISSN
0931-7597

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ChemInform Abstract: Palladium Catalyzed
✍ V. GEVORGYAN; C. KADOWAKI; M. M. SALTER; I. KADOTA; S. SAITO; Y. YAMAMOTO πŸ“‚ Article πŸ“… 2010 πŸ› John Wiley and Sons βš– 35 KB

Palladium Catalyzed Addition of Carbon Pronucleophiles to Conjugated Enynes. -A new, catalytic route to the synthesis of differently substituted allenes is developed by addition of cyano-based carbon nucleophiles to conjugated enynes. Pd2(dba)3β€’CHCl3/dppf is found to be the best catalytic system fo