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Palladium-Catalyzed Hydrocarbonation and Hydroamination of 3,3-Dihexylcyclopropene with Pronucleophiles

โœ Scribed by Nakamura, Itaru; Bajracharya, Gan B.; Yamamoto, Yoshinori


Book ID
126277619
Publisher
American Chemical Society
Year
2003
Tongue
English
Weight
77 KB
Volume
68
Category
Article
ISSN
0022-3263

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Palladium-catalyzed hydrocarbonation of
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The reaction of methyleneaziridine 1 with carbon pronucleophiles (2, H-CR 3 ) proceeds smoothly in the presence of a palladium catalyst affording the corresponding hydrocarbonation products 5 in good to high yield.

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The inter-and intrarnolecular additions of pronucleophiles to methylenecyclopropanes proceeded smoothly in the presence of catalytic amounts of Pd(PPh3) 4, affording hydrocarbonation products in good to high yields. The ring opening of methylenecyclopropanes mainly occurred at the distal position to