Ring Opening in the Palladium-Catalyzed Hydrocarbonation of Methylenecyclopropanes with Pronucleophiles
โ Scribed by Tsukada, Naofumi; Shibuya, Akinori; Nakamura, Itaru; Yamamoto, Yoshinori
- Book ID
- 121450554
- Publisher
- American Chemical Society
- Year
- 1997
- Tongue
- English
- Weight
- 187 KB
- Volume
- 119
- Category
- Article
- ISSN
- 0002-7863
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๐ SIMILAR VOLUMES
The inter-and intrarnolecular additions of pronucleophiles to methylenecyclopropanes proceeded smoothly in the presence of catalytic amounts of Pd(PPh3) 4, affording hydrocarbonation products in good to high yields. The ring opening of methylenecyclopropanes mainly occurred at the distal position to
The reaction of methyleneaziridine 1 with carbon pronucleophiles (2, H-CR 3 ) proceeds smoothly in the presence of a palladium catalyst affording the corresponding hydrocarbonation products 5 in good to high yield.