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Palladium-Catalyzed Carbonylation of Amines: Switchable Approaches to Carbamates and N,N′-Disubstituted Ureas

✍ Scribed by Zheng-Hui Guan; Hao Lei; Ming Chen; Zhi-Hui Ren; Yinjuan Bai; Yao-Yu Wang

Publisher
John Wiley and Sons
Year
2012
Tongue
English
Weight
519 KB
Volume
354
Category
Article
ISSN
1615-4150

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✍ Shuzhan Zheng; Xingao Peng; Jianming Liu; Wei Sun; Chungu Xia 📂 Article 📅 2007 🏛 John Wiley and Sons 🌐 German ⚖ 69 KB

## Abstract A highly efficient oxidative carbonylation reaction of amines to ureas was developed making use of carbene–palladium complexes in the absence of any promoter. Both aliphatic amines and aromatic amines were transformed in good to excellent yields to the expected ureas.