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(p-d) π-bonding and hyperconjugation in vinylsilane

✍ Scribed by Erich Zeeck

Publisher
Springer
Year
1974
Tongue
English
Weight
436 KB
Volume
35
Category
Article
ISSN
1432-2234

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📜 SIMILAR VOLUMES

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Halogen lone pair ionization potentials for the mainfroup IV compounds hl>i~ and MHsCI are corrected for the effects of potential and reiaxnion cneq? usin: the corrcspondinf halogen core binding energies. The corrected data indicate sig-nifican~ pzdr; bondmg in MS4 (for M = 5, Ge and Sn). sknilicant

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**A novel compound with P****C triple bond**, phenylmethylidynephosphane __(2)__, was produced by pyrolysis and trapped at −196 °C. The educt __(1)__ decomposes almost quantitatively into __(2)__ and Me~3~SiCl in a Hg‐diffusion pump vacuum at 700 °C; the educt __(3)__, on the other hand, only yield