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Analysis of pπ → dπ bonding in halogen compounds of silicon, germanium and tin

✍ Scribed by William L. Jolly

Publisher
Elsevier Science
Year
1983
Tongue
English
Weight
247 KB
Volume
100
Category
Article
ISSN
0009-2614

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✦ Synopsis

Halogen lone pair ionization potentials for the mainfroup IV compounds hl>i~ and MHsCI are corrected for the effects of potential and reiaxnion cneq? usin: the corrcspondinf halogen core binding energies. The corrected data indicate sig-nifican~ pzdr; bondmg in MS4 (for M = 5, Ge and Sn). sknilicant repulsion benicen the lone pairs and CH3 group in CH3CI. .~nd Iittlc or no pn -dx bonding in SiH,Cl and CeH,CI. ' C.rcen et al. [IO] po-mt out that the orbirals follow an approximae "b.uiccntre" rule. and de Lrzuw and de Lange

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