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Electron impact and chemical ionisation mass spectrometry in the characterisation of organometallic silicon, germanium, tin and lead compounds

✍ Scribed by Steven P. Constantine; David J. Cardin; Barrie G. Bollen

Publisher: John Wiley and Sons
Year: 2000
Tongue: English
Weight: 118 KB
Volume: 14
Category: Article
ISSN: 0951-4198
DOI: 10.1002/(sici)1097-0231(20000315)14:5<329::aid-rcm853>3.0.co;2-t

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✦ Synopsis

The electron impact and chemical ionisation mass spectra of a number of organometallic derivatives of silicon, germanium, tin and lead, incorporating inter alia 2-bis(trimethylsilyl)methylpyridyl or cyclopentadienyl ligands have been recorded. Representative spectra are presented and illustrate the utility of these mass spectrometric techniques in the characterisation of such compounds, particularly so in light of the highly informative nature arising from their fragmentation patterns and the numerous isotopes of the nuclei involved. Copyright 2000 John Wiley & Sons, Ltd.

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